Solvent Parameters

Solvent

DF

Et

Z

m

e

n

bp

mp

h #

 

1-butanol

0.361

50.2

77.7

5.84

17.51

1.3993

117.7

-88.6

2.54

 

1-chloorbutane

0.307

-

-

-

7.39 *

1.4021

78.4

-123.1

0.422

 

1-chloorpropane

0.313

-

-

-

7.7 *

1.3879

46.6

- 84.0

0.334

 

1-methyl-2-pyrrolidinon

0.368

42.2

-

13.64

32.00

1.4700

204.4

-24.4

1.67

 

1-propanol

0.369

50.7

78.3

5.54

20.33

1.3856

97.2

-126.2

1.95

 

1,1-dichloorethane

0.330

39.4

62.1

6.61

10.00

1.4064

57.3

-97.0

0.464

 

1,1,1-trichloorethane

0.300

36.2

-

5.24

7.53

1.4379

74.0

-30.4

0.793

 

1,1,3,3-tetramethylurea

0.363

41.0

-

11.58

23.45

1.4493

175.2

-1.2

139

 

1,2-diaminoethane

0.337

42.0

-

6.34

12.90

1.4568

117.3

11.3

1.54

 

1,2-dichlorobenzene

0.307

38.1

-

7.57

9.93

1.5515

180.5

-17.0

1.32

 

1,2-dichloroethane

0.326

41.9

63.4

6.20

10.36

1.4448

83.5

-35.7

0.779

 

1,2-dimethoxyethane

0.309

38.2

59.1

5.70

7.20

1.3796

85.0

-58.0

0.455

 

1,2-ethanediol

0.377

56.3

85.1

7.61

37.70

1.4318

197.3

-13.0

16.1

 

1,2,3-trimethylbenzene

0.120

33.1

-

0.00

2.28

1.4994

164.7

-44.7

0.74

 

1,4-dioxane

0.122

36.0

-

1.50

2.21

1.4224

101.3

11.8

1.18

 

Solvent

DF

Et

Z

m

e

n

bp

mp

h # 

 

2-aninoethanol

0.374

51.8

84.4

7.57

37.72

1.4539

171.0

10.5

21.1

 

2-butanol

0.359

47.1

-

5.54

16.56

1.3972

99.6

-114.7

3.10

 

2-butanon

0.370

41.3

-

9.21

18.51

1.3788

79.6

-86.7

0.405

 

2-methoxyethanol

0.359

52.3

-

6.81

16.93

1.4021

124.6

-85.1

1.60

 

2-methyl-1-propanol

0.362

49.0

-

5.97

17.93

1.3959

107.7

-108.0

3.33

 

2-methyl-2-butanol

0.283

41.9

-

5.70

5.82

1.4049

102.0

-8.8

3.55

 

2-methyl-2-propanol

0.347

43.9

71.3

5.54

12.47

1.3877

82.4

25.8

4.31

 

2-methylbutane (iso-pentane)

0.091

-

-

-

1.843 *

1.3537

27.8

-159.9

0.214

 

2-methylhexane

0.095

-

-

-

1.919 *

1.3848

90.0

-118.3

0.378 at 20C

 

2-methylpentane (iso-hexane)

0.092

-

-

-

1.881

1.3715

60.3

-153.7

0.286

 

2-pentanol

0.350

46.5

-

5.54

13.82

1.4064

119.0

-

3.47

 

2-propanol

0.370

48.6

76.3

5.54

19.92

1.3772

82.3

-88.0

2.04

 

2,2,3-trimethylpentane (iso-octaan)

0.097

-

-

-

1.962 *

1.4029

109.8

-112.3

0.51 at 33C

 

2,2,4-trimethylpentane

0.097

-

-

-

1.940 *

1.3914

99.2

-107.4

0.504 at

20 C

 

2,3-dimethylbutane (diiso-propyl)

0.093

-

-

-

1.890

1.3750

58.0

-128.5

0.361

 

Solvent

DF

Et

Z

m

e

n

bp

mp

h # 

 

2,3-dimethylpentane

0.096

-

-

-

1.939 *

1.3920

89.8

-

0.436

 

2,4-dimethylpentane

0.095

-

-

-

1.914

1.3814

80.5

-119.2

0.36

 

3-methyl-1-butanol

0.352

47.0

-

6.07

14.70

1.4071

130.5

-117.2

3.69

 

3-methylhexane

0.095

-

-

-

1.927 *

1.3886

91.8

-119.4

0.350

 

3-methylpentane **

0.093

-

-

-

1.895

1.3765

63.3

-

0.306

 

3-pentanol

0.350

54.7

-

5.47

13.02

1.4103

115.3

-75.0

4.15

 

3-pentanon

0.361

39.3

-

9.41

17.00

1.3923

102.0

-38.9

0.444

 

4-methyl-1,3-dioxol-2-on

0.387

46.6

72.4

16.7

65.10

1.4209

241.7

-48.8

2.53

 

4-methyl-2-pentanon

0.350

39.4

-

-

13.11

1.3957

116.5

-84.0

0.545

 

acetic acid

0.295

51.2

79.2

5.60

6.20

1.3719

117.9

16.7

1.06

 

acetic anhydride

0.370

43.9

-

9.41

20.70

1.3904

140.0

-73.1

0.843

 

acetone

0.374

42.2

65.5

9.54

20.70

1.3587

56.3

-94.7

0.306

 

acetonitrile

0.393

46.0

71.3

11.48

37.50

1.3441

81.6

-43.8

0.369

 

acetophenone

0.339

41.3

-

9.87

17.39

1.5342

202.0

19.6

1.68

 

aniline

0.274

44.3

-

5.04

7.00

1.5863

184.4

-5.98

3.85

 

Solvent

DF

Et

Z

m

e

n

bp

mp

h # 

 

anisole

0.229

37.2

-

4.17

4.33

1.5170

153.8

-37.5

1.06

 

benzene

0.116

34.5

54.0

0.00

2.28

1.5011

80.1

5.5

0.604

 

benzonitrile

0.353

42.0

65.0

13.51

25.20

1.5282

191.1

-12.8

1.27

 

benzyl alcohol

0.325

50.8

-

5.54

13.10

1.5404

205.5

-15.3

5.47

 

bromobenzene

0.251

37.5

59.2

5.17

5.40

1.5585

155.9

-30.8

1.07

 

butyronitrile

0.374

-

-

-

23.276

1.3838

117.9

-111.9

0.553

 

carbon disulfide

0.127

32.6

-

0.00

2.60

1.6280

46.2

-111.6

0.352

 

carbon tetrachloride

0.118

32.5

-

0.00

2.228

1.4600

76.8

-23.0

0.908

 

chlorobenzene

0.260

37.5

58.0

5.14

5.62

1.5248

131.7

-45.6

0.753

 

chloroform

0.251

39.1

63.2

3.84

4.70

1.4457

61.2

-63.6

0.537

 

cis decaline

0.111

-

-

-

2.20 *

1.4810

195.7

- 43.0

3.04

 

cyclohexane

0.100

31.2

-

0.00

2.015

1.4262

80.7

6.5

0.894

 

cyclohexanol

0.343

46.9

-

6.20

15.00

1.4641

161.1

25.2

57.5

 

cyclohexanon

0.354

40.8

-

10.04

18.30

1.4510

155.7

-32.1

2.02

 

cyclopentane

0.098

-

-

-

1.969 *

1.4065

49.3

- 93.9

0.126

 

Solvent

DF

Et

Z

m

e

n

bp

mp

h # 

 

di-n-butylether

0.194

33.4

60.1

3.94

3.10

1.3992

142.2

-95.2

0.637

 

dibutylether

0.194

-

-

-

3.10

1.3992

142.2

- 95.2

0.637

 

dichloormethane

0.319

41.1

64.7

5.17

8.93

1.4242

39.8

-95.1

0.413

 

diethyleneglycol

0.369

53.8

-

7.71

29.40

1.4475

244.8

-6.5

30.20

 

diethylether

0.251

34.6

-

4.34

4.20

1.3524

34.6

-116.3

0.224

 

diglyme

0.304

38.6

-

6.57

7.32

1.4078

159.8

-

0.989

 

dihexylether

0.170

-

-

-

2.77

1.4204

223

-

----

 

diiso-pentylether

0.175

-

-

-

2.82 *

1.4085

173.4

-

1.01 at

20 C

 

diiso-propylether

0.237

-

-

-

3.88

1.3681

68.3

- 85.5

0.379

 

diisopropylether

0.237

34.0

-

4.20

3.88

1.3681

68.3

-85.5

0.379

 

dimethylsulfoxide

0.374

45.0

71.1

13.00

46.68

1.4783

189.0

18.5

1.99

 

dipentylether

0.171

-

-

-

2.77

1.4119

190

- 69.0

0.922 at 30C

 

diphenylether

0.197

35.3

-

3.87

3.70

1.5795

258.3

26.9

2.13 at 50C

 

dipropylether

0.213

-

-

-

3.39

1.3805

89.6

-123.0

0.396

 

ethanol

0.379

51.9

79.6

5.77

24.55

1.3614

78.3

-114.1

1.07

 

Solvent

DF

Et

Z

m

e

n

bp

mp

h # 

 

ethylacetate

0.292

38.1

59.4

6.27

6.02

1.3724

77.1

-84.0

0.423

 

fluorobenzene

0.265

38.1

60.2

4.90

5.42

1.4653

84.7

-42.2

0.550

 

formamide

0.388

56.6

83.3

11.24

109.5

1.4475

210.5

2.5

3.34

 

hexamethylfosforictriamide

0.368

40.9

62.8

18.48

29.60

1.4584

235.0

7.2

3.00

 

hexanitrile

0.359

-

-

-

17.263

1.4069

163.6

- 80.3

0.912

 

iodobenzene

0.223

37.9

-

4.64

4.60

1.6200

188.3

-31.3

1.55

 

methanol

0.393

55.5

83.6

5.67

32.70

1.3284

64.7

-97.7

0.544

 

methyl acetate

0.305

40.0

-

5.37

6.68

1.3614

56.3

-98.1

1.40 at 20C

 

methylcyclohexane

0.107

-

-

-

2.071

1.4231

100.9

-126.6

0.679

 

n,n-dimethylacetamide

0.376

43.7

66.9

12.41

37.78

1.4384

166.1

-20.0

1.96

 

n,n-dimethylformamide

0.377

43.8

68.4

12.88

37.00

1.4305

152.3

-61.0

0.794

 

n-butylacetate

0.267

-

-

-

5.01 *

1.3941

126.0

- 77.9

0.685

 

n-heptane

0.095

-

-

-

1.924 *

1.3876

98.4

- 90.6

0.387

 

n-hexane

0.092

30.9

-

0.00

1.88

1.3749

68.7

-95.3

0.300

 

n-methyl aceetamide

0.393

52.0

77.9

14.65

175.70

1.4277

206.7

30.6

3.23

 

Solvent

DF

Et

Z

m

e

n

bp

mp

h # 

 

n-methylformamide

0.393

54.1

-

12.88

182.40

1.4319

183.0

-3.8

1.68

 

n-nonane

0.098

-

-

-

1.972 *

1.4054

150.8

- 53.5

0.665

 

n-octane

0.097

-

-

-

1.948 *

1.3974

125.7

- 56.8

0.508

 

n-pentane

0.090

-

-

-

1.844 *

1.3575

36.1

-129.7

0.224

 

n-pentylacetate

0.259

-

-

-

4.75 *

1.4028

149.2

-100.0

0.862

 

n-propylacetate

0.290

-

-

-

6.002 *

1.3844

101.5

- 92.5

0.544

 

nitrobenzene

0.358

42.0

-

13.44

34.82

1.5498

210.8

5.8

1.86

 

nitromethane

0.387

46.3

71.2

11.88

38.60

1.3812

101.2

-28.6

0.630

 

octanitrile

0.347

-

-

-

13.897

1.4202

205.2

- 45.6

1.81 at 15C

 

perfluoroheptane

0.098

-

-

-

1.765

1.2602

81.0

- 53.0

-

 

perfluorohexane

0.089

-

-

-

1.69

1.2515

59.0

- 74.0

-

 

perfluorooctane

0.106

-

-

-

1.85

1.2800

103.0

-

-

 

phenetol

0.226

36.4

58.9

4.54

4.20

1.5074

170.0

-29.5

1.20

 

piperidine

0.275

35.5

-

3.97

5.80

1.4525

106.4

-10.5

1.57

 

propionitrile

0.380

43.7

-

11.91

27.2

1.3658

97.4

-92.8

0.362 at 20C

 

Solvent

DF

Et

Z

m

e

n

bp

mp

 h #

 

pyridine

0.326

40.2

64.0

7.91

12.30

1.5102

115.3

-41.6

0.165

 

quinoline

0.290

39.4

-

7.27

9.00

1.6273

237.1

-14.9

3.34

 

sulfolane

0.372

44.0

77.5

16.05

44.00

1.4840

287.3

28.5

6.28 at 50C

 

tetrachloroethylene

0.118

31.9

-

0.00

2.30

1.5057

121.2

-22.4

0.844

 

tetrahydrofurane

0.308

37.4

58.8

5.84

7.58

1.4072

66.0

-108.5

0.456

 

toluene

0.126

33.9

-

1.43

2.38

1.4969

110.6

-95.0

0.560

 

trans decaline

0.110

-

-

-

2.172 *

1.4695

187.3

- 30.4

1.95

 

trichloroethylene

0.200

35.9

-

2.70

3.42

1.4760

87.2

-86.4

0.545

 

triethylamine

0.145

33.3

-

2.90

2.42

1.4010

89.5

-114.7

0.347

 

triethyleenglycol

0.362

53.5

-

9.97

23.69

1.4561

288.0

-4.3

49.0 at 20C

 

triglyme

0.305

38.9

61.3

-

7.50

1.4233

222.0

-

-

 

valeronitrile

0.366

-

-

-

19.709

1.3971

141.3

- 96.2

0.693

 

water

0.405

63.1

94.6

6.07

78.39

1.3330

100.0

0.0

 -

 

#25C (mPa s).


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Last updated March 28 2002