(add-hook 'LaTeX-mode-hook 'turn-on-reftex)
(setq reftex-plug-into-AUCTeX t)
Many useful functions are now available (click on the mouse menu, or type ALT-x reftex TAB), but these are the most important to learn by heart:
CNTR-c CNTR-c: run Latex, Bibtex, Latex-PDF, View etc.
CNTR-c CNTR-s: create a new section, subsection etc.
CNTR-c CNTR-e: create a new environment (enumerate etc.)
CNTR-c CNTR-[: refer to and find an item in your BIB-file
CNTR-c CNTR-): refer to and find a figure, section etc. in
your document